Acid sulfate soils
Acid sulfate soils are natural sediments that contain iron sulfides. They are common along the NSW coast. When disturbed or exposed to air these soils can release acid, damaging built structures and harming or killing animals and plants.
Left undisturbed, acid sulfate soils do not present any risk. But when they are exposed to air, the iron sulfides they contain react with oxygen to create sulfuric acid.
The acid makes metals in the soil, such as iron and aluminium, more soluble. These metals can be released in toxic amounts.
The acid and released metals can have many damaging effects:
- Damaging waterways and killing aquatic life – Rainfall can wash acid and toxic metals into waterways, killing organisms that are immobile (such as oysters) or that live in sediment. It can also reduce survival and growth rates of plants and animals, and promote outbreaks of disease (especially red-spot disease in fish).
- Killing plants – Very acidic soil can kill all plants growing in it.
- Corrosion – Sulfuric acid can corrode concrete, iron, steel and some aluminium alloys.
- Toxic water and dust – Acid sulfate soil and water can irritate your skin and eyes. Drinking acidic water may make animals ill.
Acid sulfate soils have economic impacts on most industries on the NSW coast, including:
- recreational fishing
- commercial fishing
- oyster growing and other aquaculture
Most of the current problems with acid sulfate soils in NSW have arisen from past practices in drainage and flood-mitigation.
Major drainage works were built on floodplains from the Tweed to the Shoalhaven Rivers from the late 1800s until the mid-1970s.
Drainage and excavation of acid sulfate soils remains a current issue for urban development, infrastructure and sand mining.
Acid sulfate soils are found in every coastal estuary in NSW.
Because of their estuarine origin, they are usually found at elevations less than 1 metre above sea level.
Acid sulfate soils are common in mangrove and saltmarsh areas. They underlie floodplains, levees and backswamps.
Acid sulfate soils may affect more than 260,000 hectares of land. About 150,000 hectares of this land are in agricultural production.
The largest areas are the coastal floodplains of northern NSW, particularly those of the Tweed, Richmond, Clarence, Macleay and Hastings rivers. Other notable locations include the Hunter and Shoalhaven rivers.
Inland acid sulfate soils occur on inland waterways, wetlands and drainage channels. Like their coastal cousins, inland acid sulfate soils develop in waterlogged, saline and anaerobic (which means living without air) conditions.
Inland acid sulfate soils became an issue during the drought in the 2000s, also known as the ‘millennium drought’. This long period of drought reduced water levels and exposed acid sulfate material which oxidised and released acid and metals into inland waterways.
The best known occurrence of inland acid sulfate soils is along the Edward-Wakool River system which extends into Victoria. These soils also occur in scattered locations throughout inland NSW, including the southern tablelands and the ACT.
Inland acid sulfate soils are often associated with salinity sites and many have not been properly identified.
The NSW Government collaborated with the Murray Darling Basin Authority, CSIRO and other basin jurisdictions, to investigate inland acid sulfate soils and their distribution. The results were published in Aspects of Quaternary geology, geomorphic history, stratigraphy, soils and hydrogeology in the Edward–Wakool channel system, with particular reference to the distribution of sulfidic channel sediments (PDF 17.4MB).
The report identifies the locations and risks of inland acid sulfate soils to rivers and streams in the Murray Darling Basin. The report is based on landform assessment, extensive fieldwork.
These maps predict the distribution of acid sulfate soils. They are based on landform assessment, extensive fieldwork and laboratory testing.
The maps show the:
- chance of acid sulfate soil occurring
- estimated depth to acid sulfate soil
- environmental risk associated with disturbing the soil
- landforms on which the soil occurs.
Obtaining and using the maps
To find out about acid sulfate soil risk and chance of occurrence look up the acid sulfate soil risk map for your area.
Acid sulfate risk maps and thematic maps are available on eSPADE.
You can download the 1:25,000 maps that show the risk of acid sulfate soils. The download includes GIS and PDF versions of the maps and guidelines for their use.
The following common activities can trigger acid sulfate soils to oxidise and produce acid.
Those involved in agriculture often need to build drainage systems for activities like:
- sugar cane and tea-tree cultivation
- dairying and other grazing
Excavation takes place when :
- building drainage works to manage floods (such as levees and floodgates)
- laying utilities (water and sewerage pipes, communication cables)
- building roads and railways.
Companies must excavate when building:
- tourist facilities.
Industries excavate when extracting sand and gravel.
Most of these works require some form of consent or approval. If you intend to carry out such works, contact your local council first. Councils have local environmental plans that specify how acid sulfate soils must be managed.
Treating acid sulfate soils
Recent research has greatly changed our understanding of how to best manage acid sulfate soils.
The NSW Acid Sulfate Soils Manual (1998) (PDF 4.3MB) outlines how to assess and manage the impacts of proposed works in areas likely to contain acid sulfate soils. (The laboratory methods in this manual have been superseded by the Laboratory Methods Guidelines (2004).)
The EPA Waste Classification Guidelines (2014) (PDF 299KB) apply to acid sulfate soils that need to be transported and treated offsite.
Current best practice
The Remediation Guidelines for Coastal Floodplains in NSW discuss practical and commonly used tools for managing acid sulfate soils including:
- use of floodgates to neutralise and dilute acid flows
- use of tidal flows to neutralise and dilute acid flows and restore estuarine areas
- construction of banks to build dry and wet containment areas.